A new 1D Zn(II) coordination polymer containing 2-amino-4,6-dimethoxypyrimidine ligand: crystal structure, Hirshfeld surface analysis, and physicochemical studies
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چکیده
منابع مشابه
Synthesis and Crystal Structure of [Pb(gly)2]n; New lead(II) Coordination Polymer with Glycine Ligand
[Pb(gly)2]n (1) (gly is the abbreviation of Glycine) have been synthesized and characterized by elemental analyses, IR, 1H NMR and 13C NMR spectroscopy. The single crystal structure of 1 show the complex is 2D coordination polymer with octahedral environment that is formed into 3D supramolecule through hydrogen bond. Structural determination of compound 1 reveals the Pb(II) ion is four coordina...
متن کاملCrystal structure and Hirshfeld surface analysis of 2-amino-4-methoxy-6-methylpyrimidinium 2-hydroxybenzoate
In the title mol-ecular salt, C6H10N3O+·C7H5O3-, the cation is protonated at the N atom lying between the amine and methyl substituents and the dihedral angle between the carboxyl group and its attached ring in the anion is 4.0 (2)°. The anion features an intra-molecular O-H⋯O hydrogen bond, which closes an S(6) ring. The cation and anion are linked by two N-H⋯O hydrogen bonds [R22(8) motif] to...
متن کامل2-[(1E)-({[(Benzylsulfanyl)methanethioyl]amino}imino)methyl]-6-methoxyphenol: crystal structure and Hirshfeld surface analysis
The title di-thio-carbazate ester, C16H16N2O2S2, comprises two almost planar residues, i.e. the phenyl ring and the remaining 14 non-H atoms (r.m.s. deviation = 0.0410 Å). These are orientated perpendicularly, forming a dihedral angle of 82.72 (5)°. An intra-molecular hy-droxy-O-H⋯N(imine) hydrogen bond, leading to an S(6) loop, is noted. An analysis of the geometric parameters is consistent wi...
متن کاملHydrazinium 2-amino-4-nitrobenzoate dihydrate: crystal structure and Hirshfeld surface analysis
In the anion of the title salt hydrate, H5N2+·C7H5N2O4-·2H2O, the carboxyl-ate and nitro groups lie out of the plane of the benzene ring to which they are bound [dihedral angles = 18.80 (10) and 8.04 (9)°, respectively], and as these groups are conrotatory, the dihedral angle between them is 26.73 (15)°. An intra-molecular amino-N-H⋯O(carboxyl-ate) hydrogen bond is noted. The main feature of th...
متن کاملSynthesis, Characterization, and Crystal Structure of a New Coordination Polymer, {[Ba2(Hpydc)2(pydc)(H20)31.H20.(112P3110}n
The reaction of barium chloride with 2, 6-pyridinedicarboxylic acid in water led to the formation of a novelpolymeric complex formulated as {[Ba2(Hpydc)2(pydc)(H20)3].H20.(H2pydc)}.(I). The crystal structure of (I)was characterized by single crystal X-ray diffraction method. The complex was crystallized in the monoclinicsystem with space group P2/c, with four molecule in unit-cell, e.g Z=4. The...
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ژورنال
عنوان ژورنال: Journal of Molecular Structure
سال: 2020
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2020.128309